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植物研究 ›› 2012, Vol. 32 ›› Issue (2): 232-236.doi: 10.7525/j.issn.1673-5102.2012.02.018

• 论文 • 上一篇    下一篇

红松应力木木材形成组织的化学组成特征分析

朱莉;石江涛*   

  1. 东北林业大学生物质材料与科学教育部重点实验室,哈尔滨 150040
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2012-03-20 发布日期:2012-03-20
  • 通讯作者: 石江涛
  • 基金资助:
     

Chemical Compound Characteristic Analysis of Wood forming Tissue from Reaction Wood of Pinus koraiensis

ZHU Li;SHI Jiang-Tao*   

  1. Key Laboratory of Biobased Material Science and Technology of Ministry of Education,Northeast Forestry University,Harbin 150040
  • Received:1900-01-01 Revised:1900-01-01 Online:2012-03-20 Published:2012-03-20
  • Contact: SHI Jiang-Tao
  • Supported by:
     

摘要: 检测分析了天然红松应力木木材形成组织的乙酰溴木质素含量,傅里叶变换红外光谱和X射线衍射图谱。结果表明:木材形成组织木质素含量小于成熟木材,应压木中木质素含量高于正常材;木材形成组织中羟基特征峰的位置有异于成熟木材,在波数1 034~1 510 cm-1处的吸收峰有明显差异,化学官能团的相对吸收强度低于成熟木材;应压木木材形成组织红外光谱特征峰的位置和峰形与对应木、正常木的基本相同;应压木全谱图各化学官能团的相对吸收强度大于正常木。木材形成组织X射线衍射强度低于成熟木材,应压木低于正常材和对应木;木材形成组织纤维素相对结晶度小于成熟木材,应压木低于正常材和对应木。说明木材形成过程中组织的化学特征是动态变化的。应力木形成中木材组织化学特征就与正常木有差异。

关键词: 未成熟木质部, 应力木, 傅里叶变换红外光谱, X射线衍射

Abstract: The acetyl bromide lignin content of wood-forming tissue from Pinus koraiensis reaction wood was detected, and the FTIR and X-ray diffraction patterns were analyzed. The results showed that the lignin content of wood-forming tissue was lower than the mature wood, and the compression wood was higher than normal. The infrared spectrum results indicated that the characteristic absorption peak sites of hydroxyl and absorption band in 1 034-1 510 cm-1 were obviously different between immature and mature woods. The relative absorption intensity of chemical functional group in immature wood was lower than mature one. The site and shape of characteristic absorption peak showed no significant difference among compression, opposite and normal woods. However, the relative absorption intensity of functional group in compression wood was higher than normal one. The diffracted intensity of wood-forming tissue was significantly lower than mature wood by X-ray diffracted pattern. Meanwhile, the diffracted intensity of compression wood was lower than opposite and normal ones. Moreover, the relative crystallinity of wood-forming tissue was significantly lower than mature xylem and it was lower in compression wood than opposite and normal ones. Hence, the chemical properties of wood-forming tissue are dynamic changing in wood formation and differences are existed between reaction and normal woods.

Key words: immature xylem, reaction wood, FTIR, XRD

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